Fluoroscence Quantum Yield given Phosphorescence Quantum Yield Solution

STEP 0: Pre-Calculation Summary
Formula Used
Fluorosecence Quantum Yield given Ph = Phosphosecence Quantum Yield*((Rate Constant of Fluoroscence*Singlet State Concentration)/(Phosphorescence Rate Constant*Concentration of Triplet State))
φFL = φph*((Kf*[MS1])/(Kp*[MT]))
This formula uses 6 Variables
Variables Used
Fluorosecence Quantum Yield given Ph - Fluorosecence Quantum Yield given Ph is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed.
Phosphosecence Quantum Yield - Phosphosecence Quantum Yield is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed.
Rate Constant of Fluoroscence - (Measured in Hertz) - Rate Constant of Fluoroscence is the rate at which spontaneous emission occurs.
Singlet State Concentration - (Measured in Mole per Cubic Meter) - Singlet State Concentration is the number of molecules present in the singlet excited state.
Phosphorescence Rate Constant - (Measured in Hertz) - Phosphorescence Rate Constant is defined as the rate at which phosphorescence occurs during emission from triplet to singlet state.
Concentration of Triplet State - (Measured in Mole per Cubic Meter) - Concentration of Triplet State is the number of molecules present in triplet state.
STEP 1: Convert Input(s) to Base Unit
Phosphosecence Quantum Yield: 5 --> No Conversion Required
Rate Constant of Fluoroscence: 750 Revolution per Second --> 750 Hertz (Check conversion here)
Singlet State Concentration: 2E-05 Mole per Liter --> 0.02 Mole per Cubic Meter (Check conversion here)
Phosphorescence Rate Constant: 45 Revolution per Second --> 45 Hertz (Check conversion here)
Concentration of Triplet State: 6.2E-05 Mole per Liter --> 0.062 Mole per Cubic Meter (Check conversion here)
STEP 2: Evaluate Formula
Substituting Input Values in Formula
φFL = φph*((Kf*[MS1])/(Kp*[MT])) --> 5*((750*0.02)/(45*0.062))
Evaluating ... ...
φFL = 26.8817204301075
STEP 3: Convert Result to Output's Unit
26.8817204301075 --> No Conversion Required
FINAL ANSWER
26.8817204301075 26.88172 <-- Fluorosecence Quantum Yield given Ph
(Calculation completed in 00.004 seconds)

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25 Emission Spectroscopy Calculators

Intensity of Fluorescence given Degree of Exciplex Formation
Go Fluorosence Intensity given Degree of Exciplex = Rate Constant of Fluoroscence*Equilibrium Constant for Coordinate Complexes*(1-Degree of Exciplex Formation)/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction)
Degree of Exciplex Formation
Go Degree of Exciplex Formation = (Equilibrium Constant for Coordinate Complexes*Quencher Concentration given Degree of Exciplex)/(1+(Equilibrium Constant for Coordinate Complexes*Quencher Concentration given Degree of Exciplex))
Fluoroscence Quantum Yield given Phosphorescence Quantum Yield
Go Fluorosecence Quantum Yield given Ph = Phosphosecence Quantum Yield*((Rate Constant of Fluoroscence*Singlet State Concentration)/(Phosphorescence Rate Constant*Concentration of Triplet State))
Fluorosence Intensity at Low Concentration of Solute
Go Fluorosence Intensity at Low Concentration = Fluorosecence Quantum Yield*Initial Intensity*2.303*Spectroscopical Molar Extinction Coefficient*Concentration at Time t*Length
Fluorescence Quantum Yield
Go Quantum Yield of Fluorescence = Rate of Radiative Reaction/(Rate of Radiative Reaction+Rate of Internal Conversion+Rate Constant of Intersystem Crossing+Quenching Constant)
Initial Intensity given Degree of Exciplex Formation
Go Initial Intensity given Degree of Exciplex = Rate Constant of Fluoroscence*Equilibrium Constant for Coordinate Complexes/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction)
Intensity Ratio
Go Intensity Ratio = 1+(Quencher Concentration given Degree of Exciplex*(Quenching Constant/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction)))
Quantum Yield of Fluorescence
Go Quantum Yield of Fluorescence = Rate Constant of Fluoroscence/(Rate Constant of Fluoroscence+Rate of Internal Conversion+Rate Constant of Intersystem Crossing)
Singlet Life Time of Radiative Process
Go Singlet Life time of Radiative Process = ((Initial Intensity/Fluorosence Intensity)-1)/(Quenching Constant*Quencher Concentration given Degree of Exciplex)
Fluoroscence Intensity without Quenching
Go Intensity Without Quenching = (Rate Constant of Fluoroscence*Absorption Intensity)/(Rate Constant of Non Radiative Reaction+Rate Constant of Fluoroscence)
Final Intensity using Stern Volmer Equation
Go Final Intensity = Initial Intensity/ (1+(Singlet Life time given Degree of Exciplex*Quenching Constant*Quencher Concentration given Degree of Exciplex))
Fluoroscence Intensity
Go Fluorosence Intensity = (Rate Constant of Fluoroscence*Absorption Intensity)/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction)
Singlet Life Time
Go Singlet Life time = 1/(Rate Constant of Intersystem Crossing+Rate of Radiative Reaction+Rate of Internal Conversion+Quenching Constant)
Collisional Energy Transfer
Go Rate of Collisional Energy Transfer = Quenching Constant*Quencher Concentration given Degree of Exciplex*Singlet State Concentration
Rate of Deactivation
Go Rate of Deactivation = (Rate Constant of Non Radiative Reaction+Rate Constant of Fluoroscence)*Singlet State Concentration
Quenching Concentration given Degree of Exciplex Formation
Go Quencher Concentration given Degree of Exciplex = ((1/(1-Degree of Exciplex Formation))-1)*(1/Equilibrium Constant for Coordinate Complexes)
Quenching Concentration
Go Quencher Concentration = ((Initial Intensity/Fluorosence Intensity)-1)/Stern Volmner Constant
Singlet Life given Degree of Exciplex Formation
Go Singlet Life time given Degree of Exciplex = 1/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction)
Rate of Phosphorescence
Go Phosphorescence Rate = Phosphorescence Rate Constant*Concentration of Triplet State
ISC Rate Constant
Go Rate Constant of ISC = Rate of Intersystem Crossing*Singlet State Concentration
Fluorescence Rate Constant
Go Rate Constant of Fluoroscence = Rate of Fluoroscence/Singlet State Concentration
Rate of Activation
Go Rate of Activation = Equilibrium Constant*(1-Degree of Dissociation of Emission)
Difference in Acidity between Ground and Excited State
Go Difference in pka = pKa of Excited State-pKa of Ground State
Equilibrium Constant for Exciplex Formation
Go Equilibrium Constant for Coordinate Complexes = 1/(1-Degree of Exciplex Formation)-1
Singlet Radiative Phosphorescence Lifetime
Go Singlet Radiative Phosphorescence Lifetime = 1/Rate of Phosphorescence

13 Quantum Yield and Singlet Llifetime Calculators

Phosphorescence Quantum Yield given Triplet Triplet Annhilation Constant
Go Phosphosecence Quantum Yield given TTA Constant = (Phosphorescence Rate Constant*ISC Quantum Yield)/(Phosphorescence Rate Constant+Rate Constant of Intersystem Crossing+Rate Constant of Triplet Triplet Anhilation)
Phosphorescence Quantum Yield given Intersystem Quantum Yield
Go Phosphorescence Quantum Yield given ISC = (Phosphorescence Rate Constant/Absorption Intensity)*(((Absorption Intensity*Triplet State Quantum Yield)/Rate Constant of Triplet Triplet Anhilation)^(1/2))
Phosphorescence Quantum Yield given Fluoroscence Quantum Yield
Go Phosphorescence Quantum Yield given φf = Fluorosecence Quantum Yield*((Phosphorescence Rate Constant*Concentration of Triplet State)/(Rate Constant of Fluoroscence*Singlet State Concentration))
Fluoroscence Quantum Yield given Phosphorescence Quantum Yield
Go Fluorosecence Quantum Yield given Ph = Phosphosecence Quantum Yield*((Rate Constant of Fluoroscence*Singlet State Concentration)/(Phosphorescence Rate Constant*Concentration of Triplet State))
Fluorescence Quantum Yield
Go Quantum Yield of Fluorescence = Rate of Radiative Reaction/(Rate of Radiative Reaction+Rate of Internal Conversion+Rate Constant of Intersystem Crossing+Quenching Constant)
Quantum Yield of Fluorescence
Go Quantum Yield of Fluorescence = Rate Constant of Fluoroscence/(Rate Constant of Fluoroscence+Rate of Internal Conversion+Rate Constant of Intersystem Crossing)
Singlet Life Time of Radiative Process
Go Singlet Life time of Radiative Process = ((Initial Intensity/Fluorosence Intensity)-1)/(Quenching Constant*Quencher Concentration given Degree of Exciplex)
Singlet Life Time
Go Singlet Life time = 1/(Rate Constant of Intersystem Crossing+Rate of Radiative Reaction+Rate of Internal Conversion+Quenching Constant)
Phosphorescence Quantum Yield
Go Quantum Yield of Phosphorescence = Rate of Radiative Reaction/(Rate of Radiative Reaction+Rate Constant of Non Radiative Reaction)
Triplet State Quantum yield
Go Quantum Yield of Triplet State = (Rate Constant of Intersystem Crossing*Singlet State Concentration)/Absorption Intensity
Singlet Life given Degree of Exciplex Formation
Go Singlet Life time given Degree of Exciplex = 1/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction)
Singlet Radiative Fluorescence Lifetime
Go Singlet Radiative Fluorescence Lifetime = 1/Rate Constant of Fluoroscence
Singlet Radiative Phosphorescence Lifetime
Go Singlet Radiative Phosphorescence Lifetime = 1/Rate of Phosphorescence

Fluoroscence Quantum Yield given Phosphorescence Quantum Yield Formula

Fluorosecence Quantum Yield given Ph = Phosphosecence Quantum Yield*((Rate Constant of Fluoroscence*Singlet State Concentration)/(Phosphorescence Rate Constant*Concentration of Triplet State))
φFL = φph*((Kf*[MS1])/(Kp*[MT]))

What is emission spectroscopy ?

Emission spectroscopy is a spectroscopic technique which examines the wavelengths of photons emitted by atoms or molecules during their transition from an excited state to a lower energy state.The technique is used to monitor the levels of different chemicals and trace elements in the environment and to determine the compositions of solids, liquids, and gases. In geoanalysis, emission spectrometry has been instrumental in the exploration of economic mineral deposits.

What is phosphorescence ?

Phosphorescence is emission of light from triplet-excited states, in which the electron in the excited orbital has the same spin orientation as the ground-state electron. Transitions to the ground state are spin-forbidden, and the emission rates are relatively slow (103 to 100 s−1).

How to Calculate Fluoroscence Quantum Yield given Phosphorescence Quantum Yield?

Fluoroscence Quantum Yield given Phosphorescence Quantum Yield calculator uses Fluorosecence Quantum Yield given Ph = Phosphosecence Quantum Yield*((Rate Constant of Fluoroscence*Singlet State Concentration)/(Phosphorescence Rate Constant*Concentration of Triplet State)) to calculate the Fluorosecence Quantum Yield given Ph, The Fluoroscence Quantum Yield given Phosphorescence Quantum Yield formula is defined as as the rate of fluoroscence intensity to the amount of radiation absorbed. Fluorosecence Quantum Yield given Ph is denoted by φFL symbol.

How to calculate Fluoroscence Quantum Yield given Phosphorescence Quantum Yield using this online calculator? To use this online calculator for Fluoroscence Quantum Yield given Phosphorescence Quantum Yield, enter Phosphosecence Quantum Yield ph), Rate Constant of Fluoroscence (Kf), Singlet State Concentration ([MS1]), Phosphorescence Rate Constant (Kp) & Concentration of Triplet State ([MT]) and hit the calculate button. Here is how the Fluoroscence Quantum Yield given Phosphorescence Quantum Yield calculation can be explained with given input values -> 26.88172 = 5*((750*0.02)/(45*0.062)).

FAQ

What is Fluoroscence Quantum Yield given Phosphorescence Quantum Yield?
The Fluoroscence Quantum Yield given Phosphorescence Quantum Yield formula is defined as as the rate of fluoroscence intensity to the amount of radiation absorbed and is represented as φFL = φph*((Kf*[MS1])/(Kp*[MT])) or Fluorosecence Quantum Yield given Ph = Phosphosecence Quantum Yield*((Rate Constant of Fluoroscence*Singlet State Concentration)/(Phosphorescence Rate Constant*Concentration of Triplet State)). Phosphosecence Quantum Yield is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed, Rate Constant of Fluoroscence is the rate at which spontaneous emission occurs, Singlet State Concentration is the number of molecules present in the singlet excited state, Phosphorescence Rate Constant is defined as the rate at which phosphorescence occurs during emission from triplet to singlet state & Concentration of Triplet State is the number of molecules present in triplet state.
How to calculate Fluoroscence Quantum Yield given Phosphorescence Quantum Yield?
The Fluoroscence Quantum Yield given Phosphorescence Quantum Yield formula is defined as as the rate of fluoroscence intensity to the amount of radiation absorbed is calculated using Fluorosecence Quantum Yield given Ph = Phosphosecence Quantum Yield*((Rate Constant of Fluoroscence*Singlet State Concentration)/(Phosphorescence Rate Constant*Concentration of Triplet State)). To calculate Fluoroscence Quantum Yield given Phosphorescence Quantum Yield, you need Phosphosecence Quantum Yield ph), Rate Constant of Fluoroscence (Kf), Singlet State Concentration ([MS1]), Phosphorescence Rate Constant (Kp) & Concentration of Triplet State ([MT]). With our tool, you need to enter the respective value for Phosphosecence Quantum Yield, Rate Constant of Fluoroscence, Singlet State Concentration, Phosphorescence Rate Constant & Concentration of Triplet State and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
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