Helmholtz Free Entropy Calculator

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✖Entropy is the measure of a system’s thermal energy per unit temperature that is unavailable for doing useful work.ⓘ Entropy [S]			+10% -10%
✖The internal energy of a thermodynamic system is the energy contained within it. It is the energy necessary to create or prepare the system in any given internal state.ⓘ Internal Energy [U]			+10% -10%
✖Temperature is the degree or intensity of heat present in a substance or object.ⓘ Temperature [T]			+10% -10%

✖The Helmholtz Free Entropy is used to express the effect of electrostatic forces in an electrolyte on its thermodynamic state.ⓘ Helmholtz Free Entropy [Φ]

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Formula

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Helmholtz Free Entropy

Formula

`"Φ" = ("S"-("U"/"T"))`

Example

`"70.21691J/K"=("71J/K"-("233.36J"/"298K"))`

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Helmholtz Free Entropy Solution

STEP 0: Pre-Calculation Summary

Formula Used

Helmholtz Free Entropy = (Entropy-(Internal Energy/Temperature))
Φ = (S-(U/T))
This formula uses 4 Variables

Variables Used

Helmholtz Free Entropy - (Measured in Joule per Kelvin) - The Helmholtz Free Entropy is used to express the effect of electrostatic forces in an electrolyte on its thermodynamic state.
Entropy - (Measured in Joule per Kelvin) - Entropy is the measure of a system’s thermal energy per unit temperature that is unavailable for doing useful work.
Internal Energy - (Measured in Joule) - The internal energy of a thermodynamic system is the energy contained within it. It is the energy necessary to create or prepare the system in any given internal state.
Temperature - (Measured in Kelvin) - Temperature is the degree or intensity of heat present in a substance or object.

STEP 1: Convert Input(s) to Base Unit

Entropy: 71 Joule per Kelvin --> 71 Joule per Kelvin No Conversion Required
Internal Energy: 233.36 Joule --> 233.36 Joule No Conversion Required
Temperature: 298 Kelvin --> 298 Kelvin No Conversion Required

STEP 2: Evaluate Formula

Substituting Input Values in Formula

Φ = (S-(U/T)) --> (71-(233.36/298))

Evaluating ... ...

Φ = 70.2169127516779

STEP 3: Convert Result to Output's Unit

70.2169127516779 Joule per Kelvin --> No Conversion Required

FINAL ANSWER

70.2169127516779 ≈ 70.21691 Joule per Kelvin <-- Helmholtz Free Entropy

(Calculation completed in 00.004 seconds)

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Created by Prashant Singh

K J Somaiya College of science (K J Somaiya), Mumbai

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< 14 Chemical Thermodynamics Calculators

Gibbs Free Entropy

Go Gibbs Free Entropy = Entropy-((Internal Energy+(Pressure*Volume))/Temperature)

Volume given Gibbs and Helmholtz Free Entropy

Go Volume given Gibbs and Helmholtz Entropy = ((Helmholtz Entropy-Gibbs Free Entropy)*Temperature)/Pressure

Gibbs Free Entropy given Helmholtz Free Entropy

Go Gibbs Free Entropy = Helmholtz Free Entropy-((Pressure*Volume)/Temperature)

Gibbs Free Energy Change

Go Gibbs Free Energy Change = -Number of Moles of Electron*[Faraday]/Electrode Potential of a System

Electrode Potential given Gibbs Free Energy

Go Electrode Potential = -Gibbs Free Energy Change/(Number of Moles of Electron*[Faraday])

Cell Potential given Change in Gibbs Free Energy

Go Cell Potential = -Gibbs Free Energy Change/(Moles of Electron Transferred*[Faraday])

Classical Part of Gibbs Free Entropy given Electric Part

Go Classical part gibbs free entropy = (Gibbs Free Entropy of System-Electric part gibbs free entropy)

Helmholtz Free Entropy

Go Helmholtz Free Entropy = (Entropy-(Internal Energy/Temperature))

Entropy given Internal Energy and Helmholtz Free Entropy

Go Entropy = Helmholtz Free Entropy+(Internal Energy/Temperature)

Classical Part of Helmholtz Free Entropy given Electric Part

Go Classical Helmholtz Free Entropy = (Helmholtz Free Entropy-Electric Helmholtz Free Entropy)

Gibbs Free Energy

Go Gibbs Free Energy = Enthalpy-Temperature*Entropy

Helmholtz Free Energy given Helmholtz Free Entropy and Temperature

Go Helmholtz Free Energy of System = -(Helmholtz Free Entropy*Temperature)

Helmholtz Free Entropy given Helmholtz Free Energy

Go Helmholtz Free Entropy = -(Helmholtz Free Energy of System/Temperature)

Gibbs Free Energy given Gibbs Free Entropy

Go Gibbs Free Energy = (-Gibbs Free Entropy*Temperature)

< 17 Second Laws of Thermodynamics Calculators

Volume given Gibbs and Helmholtz Free Entropy

Go Volume given Gibbs and Helmholtz Entropy = ((Helmholtz Entropy-Gibbs Free Entropy)*Temperature)/Pressure

Gibbs Free Entropy given Helmholtz Free Entropy

Go Gibbs Free Entropy = Helmholtz Free Entropy-((Pressure*Volume)/Temperature)

Pressure given Gibbs and Helmholtz Free Entropy

Go Pressure = ((Helmholtz Free Entropy-Gibbs Free Entropy)*Temperature)/Volume

Gibbs Free Energy Change

Go Gibbs Free Energy Change = -Number of Moles of Electron*[Faraday]/Electrode Potential of a System

Electrode Potential given Gibbs Free Energy

Go Electrode Potential = -Gibbs Free Energy Change/(Number of Moles of Electron*[Faraday])

Cell Potential given Change in Gibbs Free Energy

Go Cell Potential = -Gibbs Free Energy Change/(Moles of Electron Transferred*[Faraday])

Classical Part of Gibbs Free Entropy given Electric Part

Go Classical part gibbs free entropy = (Gibbs Free Entropy of System-Electric part gibbs free entropy)

Helmholtz Free Entropy

Go Helmholtz Free Entropy = (Entropy-(Internal Energy/Temperature))

Entropy given Internal Energy and Helmholtz Free Entropy

Go Entropy = Helmholtz Free Entropy+(Internal Energy/Temperature)

Internal Energy given Helmholtz Free Entropy and Entropy

Go Internal Energy = (Entropy-Helmholtz Free Entropy)*Temperature

Classical Part of Helmholtz Free Entropy given Electric Part

Go Classical Helmholtz Free Entropy = (Helmholtz Free Entropy-Electric Helmholtz Free Entropy)

Electric Part of Helmholtz Free Entropy given Classical Part

Go Electric Helmholtz Free Entropy = (Helmholtz Free Entropy-Classical Helmholtz Free Entropy)

Helmholtz Free Entropy given Classical and Electric Part

Go Helmholtz Free Entropy = (Classical Helmholtz Free Entropy+Electric Helmholtz Free Entropy)

Gibbs Free Energy

Go Gibbs Free Energy = Enthalpy-Temperature*Entropy

Helmholtz Free Energy given Helmholtz Free Entropy and Temperature

Go Helmholtz Free Energy of System = -(Helmholtz Free Entropy*Temperature)

Helmholtz Free Entropy given Helmholtz Free Energy

Go Helmholtz Free Entropy = -(Helmholtz Free Energy of System/Temperature)

Gibbs Free Energy given Gibbs Free Entropy

Go Gibbs Free Energy = (-Gibbs Free Entropy*Temperature)

Helmholtz Free Entropy Formula

Helmholtz Free Entropy = (Entropy-(Internal Energy/Temperature))
Φ = (S-(U/T))

What is Debye–Huckel limiting law?

The chemists Peter Debye and Erich Hückel noticed that solutions that contain ionic solutes do not behave ideally even at very low concentrations. So, while the concentration of the solutes is fundamental to the calculation of the dynamics of a solution, they theorized that an extra factor that they termed gamma is necessary to the calculation of the activity coefficients of the solution. Hence they developed the Debye–Hückel equation and Debye–Hückel limiting law. The activity is only proportional to the concentration and is altered by a factor known as the activity coefficient. This factor takes into account the interaction energy of ions in the solution.

How to Calculate Helmholtz Free Entropy?

Helmholtz Free Entropy calculator uses Helmholtz Free Entropy = (Entropy-(Internal Energy/Temperature)) to calculate the Helmholtz Free Entropy, The Helmholtz free entropy formula is defined as the subtraction of the ratio of internal energy and temperature from the entropy of the system. Helmholtz Free Entropy is denoted by Φ symbol.

How to calculate Helmholtz Free Entropy using this online calculator? To use this online calculator for Helmholtz Free Entropy, enter Entropy (S), Internal Energy (U) & Temperature (T) and hit the calculate button. Here is how the Helmholtz Free Entropy calculation can be explained with given input values -> 70.21812 = (71-(233.36/298)).

FAQ

What is Helmholtz Free Entropy?

The Helmholtz free entropy formula is defined as the subtraction of the ratio of internal energy and temperature from the entropy of the system and is represented as Φ = (S-(U/T)) or Helmholtz Free Entropy = (Entropy-(Internal Energy/Temperature)). Entropy is the measure of a system’s thermal energy per unit temperature that is unavailable for doing useful work, The internal energy of a thermodynamic system is the energy contained within it. It is the energy necessary to create or prepare the system in any given internal state & Temperature is the degree or intensity of heat present in a substance or object.

How to calculate Helmholtz Free Entropy?

The Helmholtz free entropy formula is defined as the subtraction of the ratio of internal energy and temperature from the entropy of the system is calculated using Helmholtz Free Entropy = (Entropy-(Internal Energy/Temperature)). To calculate Helmholtz Free Entropy, you need Entropy (S), Internal Energy (U) & Temperature (T). With our tool, you need to enter the respective value for Entropy, Internal Energy & Temperature and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.

How many ways are there to calculate Helmholtz Free Entropy?

In this formula, Helmholtz Free Entropy uses Entropy, Internal Energy & Temperature. We can use 3 other way(s) to calculate the same, which is/are as follows -

Helmholtz Free Entropy = -(Helmholtz Free Energy of System/Temperature)
Helmholtz Free Entropy = -(Helmholtz Free Energy of System/Temperature)
Helmholtz Free Entropy = (Classical Helmholtz Free Entropy+Electric Helmholtz Free Entropy)

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