Vibrational Energy of Linear Molecule Solution

STEP 0: Pre-Calculation Summary
Formula Used
Vibrational Energy = ((3*Atomicity)-5)*([BoltZ]*Temperature)
Evf = ((3*N)-5)*([BoltZ]*T)
This formula uses 1 Constants, 3 Variables
Constants Used
[BoltZ] - Boltzmann constant Value Taken As 1.38064852E-23
Variables Used
Vibrational Energy - (Measured in Joule) - Vibrational Energy is the total energy of the respective rotation-vibration levels of a diatomic molecule.
Atomicity - The Atomicity is defined as the total number of atoms present in a molecule or element.
Temperature - (Measured in Kelvin) - Temperature is the degree or intensity of heat present in a substance or object.
STEP 1: Convert Input(s) to Base Unit
Atomicity: 3 --> No Conversion Required
Temperature: 85 Kelvin --> 85 Kelvin No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
Evf = ((3*N)-5)*([BoltZ]*T) --> ((3*3)-5)*([BoltZ]*85)
Evaluating ... ...
Evf = 4.694204968E-21
STEP 3: Convert Result to Output's Unit
4.694204968E-21 Joule --> No Conversion Required
FINAL ANSWER
4.694204968E-21 4.7E-21 Joule <-- Vibrational Energy
(Calculation completed in 00.004 seconds)

Credits

Created by Prerana Bakli
University of Hawaiʻi at Mānoa (UH Manoa), Hawaii, USA
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Verified by Akshada Kulkarni
National Institute of Information Technology (NIIT), Neemrana
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24 Equipartition Principle and Heat Capacity Calculators

Internal Molar Energy of Non-Linear Molecule
Go Molar Internal Energy = ((3/2)*[R]*Temperature)+((0.5*Moment of Inertia along Y-axis*(Angular Velocity along Y-axis^2))+(0.5*Moment of Inertia along Z-axis*(Angular Velocity along Z-axis^2))+(0.5*Moment of Inertia along X-axis*(Angular Velocity along X-axis^2)))+((3*Atomicity)-6)*([R]*Temperature)
Average Thermal Energy of Non-linear Polyatomic Gas Molecule
Go Thermal Energy = ((3/2)*[BoltZ]*Temperature)+((0.5*Moment of Inertia along Y-axis*(Angular Velocity along Y-axis^2))+(0.5*Moment of Inertia along Z-axis*(Angular Velocity along Z-axis^2)))+((3*Atomicity)-6)*([BoltZ]*Temperature)
Average Thermal Energy of Linear Polyatomic Gas Molecule
Go Thermal Energy = ((3/2)*[BoltZ]*Temperature)+((0.5*Moment of Inertia along Y-axis*(Angular Velocity along Y-axis^2))+(0.5*Moment of Inertia along Z-axis*(Angular Velocity along Z-axis^2)))+((3*Atomicity)-5)*([BoltZ]*Temperature)
Internal Molar Energy of Linear Molecule
Go Molar Internal Energy = ((3/2)*[R]*Temperature)+((0.5*Moment of Inertia along Y-axis*(Angular Velocity along Y-axis^2))+(0.5*Moment of Inertia along Z-axis*(Angular Velocity along Z-axis^2)))+((3*Atomicity)-5)*([R]*Temperature)
Rotational Energy of Non-Linear Molecule
Go Rotational Energy = (0.5*Moment of Inertia along Y-axis*Angular Velocity along Y-axis^2)+(0.5*Moment of Inertia along Z-axis*Angular Velocity along Z-axis^2)+(0.5*Moment of Inertia along X-axis*Angular Velocity along X-axis^2)
Translational Energy
Go Translational Energy = ((Momentum along X-axis^2)/(2*Mass))+((Momentum along Y-axis^2)/(2*Mass))+((Momentum along Z-axis^2)/(2*Mass))
Rotational Energy of Linear Molecule
Go Rotational Energy = (0.5*Moment of Inertia along Y-axis*(Angular Velocity along Y-axis^2))+(0.5*Moment of Inertia along Z-axis*(Angular Velocity along Z-axis^2))
Vibrational Energy Modeled as Harmonic Oscillator
Go Vibrational Energy = ((Momentum of Harmonic Oscillator^2)/(2*Mass))+(0.5*Spring Constant*(Change in Position^2))
Average Thermal Energy of Non-linear polyatomic Gas Molecule given Atomicity
Go Thermal Energy given Atomicity = ((6*Atomicity)-6)*(0.5*[BoltZ]*Temperature)
Average Thermal Energy of Linear Polyatomic Gas Molecule given Atomicity
Go Thermal Energy given Atomicity = ((6*Atomicity)-5)*(0.5*[BoltZ]*Temperature)
Total Kinetic Energy
Go Total Energy = Translational Energy+Rotational Energy+Vibrational Energy
Specific Heat Capacity given heat capacity
Go Specific Heat Capacity = Heat Capacity/(Mass*Change in Temperature)
Internal Molar Energy of Non-Linear Molecule given Atomicity
Go Molar Internal Energy = ((6*Atomicity)-6)*(0.5*[R]*Temperature)
Internal Molar Energy of Linear Molecule given Atomicity
Go Molar Internal Energy = ((6*Atomicity)-5)*(0.5*[R]*Temperature)
Heat Capacity
Go Heat Capacity = Mass*Specific Heat Capacity*Change in Temperature
Molar Vibrational Energy of Non-Linear Molecule
Go Vibrational Molar Energy = ((3*Atomicity)-6)*([R]*Temperature)
Molar Vibrational Energy of Linear Molecule
Go Vibrational Molar Energy = ((3*Atomicity)-5)*([R]*Temperature)
Vibrational Energy of Non-Linear Molecule
Go Vibrational Energy = ((3*Atomicity)-6)*([BoltZ]*Temperature)
Vibrational Energy of Linear Molecule
Go Vibrational Energy = ((3*Atomicity)-5)*([BoltZ]*Temperature)
Heat Capacity given Specific Heat Capacity
Go Heat Capacity = Specific Heat Capacity*Mass
Number of Modes in Non-Linear Molecule
Go Number of Normal modes for Non Linear = (6*Atomicity)-6
Vibrational Mode of Non-Linear Molecule
Go Number of Normal modes = (3*Atomicity)-6
Vibrational Mode of Linear Molecule
Go Number of Normal modes = (3*Atomicity)-5
Number of Modes in Linear Molecule
Go Number of Modes = (6*Atomicity)-5

Vibrational Energy of Linear Molecule Formula

Vibrational Energy = ((3*Atomicity)-5)*([BoltZ]*Temperature)
Evf = ((3*N)-5)*([BoltZ]*T)

What is the statement of Equipartition Theorem?

The original concept of equipartition was that the total kinetic energy of a system is shared equally among all of its independent parts, on the average, once the system has reached thermal equilibrium. Equipartition also makes quantitative predictions for these energies. The key point is that the kinetic energy is quadratic in the velocity. The equipartition theorem shows that in thermal equilibrium, any degree of freedom (such as a component of the position or velocity of a particle) which appears only quadratically in the energy has an average energy of ​1⁄2kBT and therefore contributes ​1⁄2kB to the system's heat capacity.

How to Calculate Vibrational Energy of Linear Molecule?

Vibrational Energy of Linear Molecule calculator uses Vibrational Energy = ((3*Atomicity)-5)*([BoltZ]*Temperature) to calculate the Vibrational Energy, The Vibrational Energy of Linear Molecule is defined as the kinetic energy an object has due to its vibrational motion. Vibrational Energy is denoted by Evf symbol.

How to calculate Vibrational Energy of Linear Molecule using this online calculator? To use this online calculator for Vibrational Energy of Linear Molecule, enter Atomicity (N) & Temperature (T) and hit the calculate button. Here is how the Vibrational Energy of Linear Molecule calculation can be explained with given input values -> 4.7E-21 = ((3*3)-5)*([BoltZ]*85).

FAQ

What is Vibrational Energy of Linear Molecule?
The Vibrational Energy of Linear Molecule is defined as the kinetic energy an object has due to its vibrational motion and is represented as Evf = ((3*N)-5)*([BoltZ]*T) or Vibrational Energy = ((3*Atomicity)-5)*([BoltZ]*Temperature). The Atomicity is defined as the total number of atoms present in a molecule or element & Temperature is the degree or intensity of heat present in a substance or object.
How to calculate Vibrational Energy of Linear Molecule?
The Vibrational Energy of Linear Molecule is defined as the kinetic energy an object has due to its vibrational motion is calculated using Vibrational Energy = ((3*Atomicity)-5)*([BoltZ]*Temperature). To calculate Vibrational Energy of Linear Molecule, you need Atomicity (N) & Temperature (T). With our tool, you need to enter the respective value for Atomicity & Temperature and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
How many ways are there to calculate Vibrational Energy?
In this formula, Vibrational Energy uses Atomicity & Temperature. We can use 2 other way(s) to calculate the same, which is/are as follows -
  • Vibrational Energy = ((Momentum of Harmonic Oscillator^2)/(2*Mass))+(0.5*Spring Constant*(Change in Position^2))
  • Vibrational Energy = ((3*Atomicity)-6)*([BoltZ]*Temperature)
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