Phosphorescence Quantum Yield given Fluoroscence Quantum Yield Calculator

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✖Fluorosecence Quantum Yield is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed.ⓘ Fluorosecence Quantum Yield [φ_f]			+10% -10%
✖Phosphorescence Rate Constant is defined as the rate at which phosphorescence occurs during emission from triplet to singlet state.ⓘ Phosphorescence Rate Constant [K_p]			+10% -10%
✖Concentration of Triplet State is the number of molecules present in triplet state.ⓘ Concentration of Triplet State [[M_T]]			+10% -10%
✖Rate Constant of Fluoroscence is the rate at which spontaneous emission occurs.ⓘ Rate Constant of Fluoroscence [K_f]			+10% -10%
✖Singlet State Concentration is the number of molecules present in the singlet excited state.ⓘ Singlet State Concentration [[M_S1]]			+10% -10%

✖Phosphosecence Quantum Yield is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed.ⓘ Phosphorescence Quantum Yield given Fluoroscence Quantum Yield [φ_ph]

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Formula

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Phosphorescence Quantum Yield given Fluoroscence Quantum Yield

Formula

`"φ"_{"ph"} = "φ"_{"f"}*(("K"_{"p"}*("[M"_{"T"}"]"))/("K"_{"f"}*("[M"_{"S1"}"]")))`

Example

`"42"="3"*(("45r/s"*"350mol/L")/("25r/s"*"45mol/L"))`

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Phosphorescence Quantum Yield given Fluoroscence Quantum Yield Solution

STEP 0: Pre-Calculation Summary

Formula Used

Phosphosecence Quantum Yield = Fluorosecence Quantum Yield*((Phosphorescence Rate Constant*Concentration of Triplet State)/(Rate Constant of Fluoroscence*Singlet State Concentration))
φ_ph = φ_f*((K_p*[M_T])/(K_f*[M_S1]))
This formula uses 6 Variables

Variables Used

Phosphosecence Quantum Yield - Phosphosecence Quantum Yield is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed.
Fluorosecence Quantum Yield - Fluorosecence Quantum Yield is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed.
Phosphorescence Rate Constant - (Measured in Hertz) - Phosphorescence Rate Constant is defined as the rate at which phosphorescence occurs during emission from triplet to singlet state.
Concentration of Triplet State - (Measured in Mole per Cubic Meter) - Concentration of Triplet State is the number of molecules present in triplet state.
Rate Constant of Fluoroscence - (Measured in Hertz) - Rate Constant of Fluoroscence is the rate at which spontaneous emission occurs.
Singlet State Concentration - (Measured in Mole per Cubic Meter) - Singlet State Concentration is the number of molecules present in the singlet excited state.

STEP 1: Convert Input(s) to Base Unit

Fluorosecence Quantum Yield: 3 --> No Conversion Required
Phosphorescence Rate Constant: 45 Revolution per Second --> 45 Hertz (Check conversion here)
Concentration of Triplet State: 350 Mole per Liter --> 350000 Mole per Cubic Meter (Check conversion here)
Rate Constant of Fluoroscence: 25 Revolution per Second --> 25 Hertz (Check conversion here)
Singlet State Concentration: 45 Mole per Liter --> 45000 Mole per Cubic Meter (Check conversion here)

STEP 2: Evaluate Formula

Substituting Input Values in Formula

φ_ph = φ_f*((K_p*[M_T])/(K_f*[M_S1])) --> 3*((45*350000)/(25*45000))

Evaluating ... ...

φ_ph = 42

STEP 3: Convert Result to Output's Unit

42 --> No Conversion Required

FINAL ANSWER

42 <-- Phosphosecence Quantum Yield

(Calculation completed in 00.016 seconds)

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< 24 Physical spectroscopy Calculators

Singlet State Concentration

Go Singlet State Concentration = Absorption Intensity/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction+Rate Constant of Intersystem Crossing+Rate Constant of Internal Conversion)

Phosphorescence Quantum Yield given Intersystem Quantum Yield

Go Phosphosecence Quantum Yield = (Phosphorescence Rate Constant/Absorption Intensity)*(((Absorption Intensity*Triplet State Quantum Yield)/Rate Constant of Triplet Triplet Anhilation)^(1/2))

Phosphorescence Quantum Yield given Fluoroscence Quantum Yield

Go Phosphosecence Quantum Yield = Fluorosecence Quantum Yield*((Phosphorescence Rate Constant*Concentration of Triplet State)/(Rate Constant of Fluoroscence*Singlet State Concentration))

Fluoroscence Quantum Yield given Phosphorescence Quantum Yield

Go Fluorosecence Quantum Yield = Phosphosecence Quantum Yield*((Rate Constant of Fluoroscence*Singlet State Concentration)/(Phosphorescence Rate Constant*Concentration of Triplet State))

Fluorescence Quantum Yield

Go Fluorosecence Quantum Yield = Rate of Radiative Reaction/(Rate of Radiative Reaction+Rate of Internal Conversion+Rate Constant of Intersystem Crossing+Quenching Constant)

Fluorosence Intensity at Low Concentration of Solute

Go Fluorosence Intensity = Fluorosecence Quantum Yield*Initial Intensity*2.303*Spectroscopical Molar Extinction Coefficient*Concentration at Time t*Length

Quantum Yield of Fluorescence

Go Fluorosecence Quantum Yield = Rate Constant of Fluoroscence/(Rate Constant of Fluoroscence+Rate of Internal Conversion+Rate Constant of Intersystem Crossing)

Fluoroscence Intensity without Quenching

Go Intensity Without Quenching = (Rate Constant of Fluoroscence*Absorption Intensity)/(Rate Constant of Non Radiative Reaction+Rate Constant of Fluoroscence)

Intensity Ratio

Go Intensity Ratio = 1+(Quencher Concentration*(Quenching Constant/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction)))

Singlet Life Time

Go Singlet Life time = 1/(Rate Constant of Intersystem Crossing+Rate of Radiative Reaction+Rate of Internal Conversion+Quenching Constant)

Final Intensity using Stern Volmer Equation

Go Final Intensity = Initial Intensity/ (1+(Singlet Life time*Quenching Constant*Quencher Concentration))

Phosphorescence Quantum Yield

Go Phosphosecence Quantum Yield = Rate of Radiative Reaction/(Rate of Radiative Reaction+Rate Constant of Non Radiative Reaction)

Rate of Deactivation

Go Rate of Deactivation = (Rate Constant of Non Radiative Reaction+Rate Constant of Fluoroscence)*Singlet State Concentration

Triplet State Quantum yield

Go Triplet State Quantum Yield = (Rate Constant of Intersystem Crossing*Singlet State Concentration)/Absorption Intensity

Collisional Energy Transfer

Go Rate of Collisional Energy Transfer = Quenching Constant*Quencher Concentration*Singlet State Concentration

ISC Rate Constant

Go Rate Constant of Intersystem Crossing = Rate of Intersystem Crossing*Singlet State Concentration

Rate of ISC

Go Rate of Intersystem Crossing = Rate Constant of Intersystem Crossing*Singlet State Concentration

Phosphorescence Rate Constant

Go Phosphorescence Rate Constant = Rate of Phosphorescence/Concentration of Triplet State

Rate of Phosphorescence

Go Rate of Phosphorescence = Phosphorescence Rate Constant*Concentration of Triplet State

Fluorescence Rate Constant

Go Rate Constant of Fluoroscence = Rate of Fluoroscence/Singlet State Concentration

Rate of Activation

Go Rate of Activation = Equilibrium Constant*(1-Degree of Dissociation of Emission)

Difference in Acidity between Ground and Excited State

Go Difference in pka = pKa of Excited State-pKa of Ground State

Singlet Radiative Fluorescence Lifetime

Go Singlet Life time = 1/Rate Constant of Fluoroscence

Singlet Radiative Phosphorescence Lifetime

Go Singlet Life time = 1/Rate of Phosphorescence

Phosphorescence Quantum Yield given Fluoroscence Quantum Yield Formula

What is Quantum yield ?

Quantum yield (Φ) is defined as the ratio of the number of photons emitted to the number of photons absorbed. Notably, quantum yield is independent of instrument settings and describes how efficiently a fluorophore converts the excitation light into fluorescence.

What is phosphorescence ?

Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluorescence, a phosphorescent material does not immediately reemit the radiation it absorbs.

How to Calculate Phosphorescence Quantum Yield given Fluoroscence Quantum Yield?

Phosphorescence Quantum Yield given Fluoroscence Quantum Yield calculator uses Phosphosecence Quantum Yield = Fluorosecence Quantum Yield*((Phosphorescence Rate Constant*Concentration of Triplet State)/(Rate Constant of Fluoroscence*Singlet State Concentration)) to calculate the Phosphosecence Quantum Yield, The Phosphorescence Quantum Yield given Fluoroscence Quantum Yield formula is defined as the rate of phosphorescence intensity to the amount of radiation absorbed. Phosphosecence Quantum Yield is denoted by φ_ph symbol.

How to calculate Phosphorescence Quantum Yield given Fluoroscence Quantum Yield using this online calculator? To use this online calculator for Phosphorescence Quantum Yield given Fluoroscence Quantum Yield, enter Fluorosecence Quantum Yield (φ_f), Phosphorescence Rate Constant (K_p), Concentration of Triplet State ([M_T]), Rate Constant of Fluoroscence (K_f) & Singlet State Concentration ([M_S1]) and hit the calculate button. Here is how the Phosphorescence Quantum Yield given Fluoroscence Quantum Yield calculation can be explained with given input values -> 42 = 3*((45*350000)/(25*45000)).

FAQ

What is Phosphorescence Quantum Yield given Fluoroscence Quantum Yield?

The Phosphorescence Quantum Yield given Fluoroscence Quantum Yield formula is defined as the rate of phosphorescence intensity to the amount of radiation absorbed and is represented as φ_ph = φ_f*((K_p*[M_T])/(K_f*[M_S1])) or Phosphosecence Quantum Yield = Fluorosecence Quantum Yield*((Phosphorescence Rate Constant*Concentration of Triplet State)/(Rate Constant of Fluoroscence*Singlet State Concentration)). Fluorosecence Quantum Yield is a measure of the efficiency of photon emission as defined by the ratio of the number of photons emitted to the number of photons absorbed, Phosphorescence Rate Constant is defined as the rate at which phosphorescence occurs during emission from triplet to singlet state, Concentration of Triplet State is the number of molecules present in triplet state, Rate Constant of Fluoroscence is the rate at which spontaneous emission occurs & Singlet State Concentration is the number of molecules present in the singlet excited state.

How to calculate Phosphorescence Quantum Yield given Fluoroscence Quantum Yield?

The Phosphorescence Quantum Yield given Fluoroscence Quantum Yield formula is defined as the rate of phosphorescence intensity to the amount of radiation absorbed is calculated using Phosphosecence Quantum Yield = Fluorosecence Quantum Yield*((Phosphorescence Rate Constant*Concentration of Triplet State)/(Rate Constant of Fluoroscence*Singlet State Concentration)). To calculate Phosphorescence Quantum Yield given Fluoroscence Quantum Yield, you need Fluorosecence Quantum Yield (φ_f), Phosphorescence Rate Constant (K_p), Concentration of Triplet State ([M_T]), Rate Constant of Fluoroscence (K_f) & Singlet State Concentration ([M_S1]). With our tool, you need to enter the respective value for Fluorosecence Quantum Yield, Phosphorescence Rate Constant, Concentration of Triplet State, Rate Constant of Fluoroscence & Singlet State Concentration and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.

How many ways are there to calculate Phosphosecence Quantum Yield?

In this formula, Phosphosecence Quantum Yield uses Fluorosecence Quantum Yield, Phosphorescence Rate Constant, Concentration of Triplet State, Rate Constant of Fluoroscence & Singlet State Concentration. We can use 3 other way(s) to calculate the same, which is/are as follows -

Phosphosecence Quantum Yield = Rate of Radiative Reaction/(Rate of Radiative Reaction+Rate Constant of Non Radiative Reaction)
Phosphosecence Quantum Yield = (Phosphorescence Rate Constant/Absorption Intensity)*(((Absorption Intensity*Triplet State Quantum Yield)/Rate Constant of Triplet Triplet Anhilation)^(1/2))
Phosphosecence Quantum Yield = (Phosphorescence Rate Constant*ISC Quantum Yield)/(Phosphorescence Rate Constant+Rate Constant of Intersystem Crossing+Rate Constant of Triplet Triplet Anhilation)

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