LCM calculator

Singlet State Concentration Calculator

Chemistry Engineering Financial Health More >>

↳

Physical Chemistry Analytical chemistry Atmospheric Chemistry Atomic structure More >>

⤿

Physical spectroscopy Gaseous state Vapour Pressure

⤿

Emission Spectroscopy Raman spectroscopy Rotational Spectroscopy Vibrational Spectroscopy

⤿

Fluoroscence and Phosphorescence Quantum Yield and Singlet Llifetime

✖Absorption Intensity obtained by integrating the area under the absorption line—is proportional to the amount of the absorbing substance present.ⓘ Absorption Intensity [I_a]			+10% -10%
✖Rate Constant of Fluoroscence is the rate at which spontaneous emission occurs.ⓘ Rate Constant of Fluoroscence [K_f]			+10% -10%
✖Rate Constant of Non Radiative Reaction is defined as the rate at which deactivation occurs in the form of heat energy.ⓘ Rate Constant of Non Radiative Reaction [K_NR]			+10% -10%
✖Rate Constant of Intersystem Crossing is the rate of decay from excited singlet electronic state to triplet state.ⓘ Rate Constant of Intersystem Crossing [K_ISC]			+10% -10%
✖Rate Constant of Internal Conversion is the rate of decay from excited singlet electronic state to triplet state.ⓘ Rate Constant of Internal Conversion [K_IC]			+10% -10%

✖Concentration of Singlet State is the number of molecules present in the singlet excited state.ⓘ Singlet State Concentration [[M_Ss1]]

⎘ Copy

👎

Formula

LaTeX

Reset

👍

Download Physical Chemistry Formula PDF PDF Image

Singlet State Concentration Solution

STEP 0: Pre-Calculation Summary

Formula Used

Concentration of Singlet State = Absorption Intensity/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction+Rate Constant of Intersystem Crossing+Rate Constant of Internal Conversion)
[M_Ss1] = I_a/(K_f+K_NR+K_ISC+K_IC)
This formula uses 6 Variables

Variables Used

Concentration of Singlet State - (Measured in Mole per Cubic Meter) - Concentration of Singlet State is the number of molecules present in the singlet excited state.
Absorption Intensity - (Measured in Watt per Square Meter) - Absorption Intensity obtained by integrating the area under the absorption line—is proportional to the amount of the absorbing substance present.
Rate Constant of Fluoroscence - (Measured in Hertz) - Rate Constant of Fluoroscence is the rate at which spontaneous emission occurs.
Rate Constant of Non Radiative Reaction - (Measured in Hertz) - Rate Constant of Non Radiative Reaction is defined as the rate at which deactivation occurs in the form of heat energy.
Rate Constant of Intersystem Crossing - (Measured in Hertz) - Rate Constant of Intersystem Crossing is the rate of decay from excited singlet electronic state to triplet state.
Rate Constant of Internal Conversion - (Measured in Hertz) - Rate Constant of Internal Conversion is the rate of decay from excited singlet electronic state to triplet state.

STEP 1: Convert Input(s) to Base Unit

Absorption Intensity: 250 Watt per Square Meter --> 250 Watt per Square Meter No Conversion Required
Rate Constant of Fluoroscence: 750 Revolution per Second --> 750 Hertz (Check conversion here)
Rate Constant of Non Radiative Reaction: 35 Revolution per Second --> 35 Hertz (Check conversion here)
Rate Constant of Intersystem Crossing: 64000 Revolution per Second --> 64000 Hertz (Check conversion here)
Rate Constant of Internal Conversion: 45.5 Revolution per Second --> 45.5 Hertz (Check conversion here)

STEP 2: Evaluate Formula

Substituting Input Values in Formula

[M_Ss1] = I_a/(K_f+K_NR+K_ISC+K_IC) --> 250/(750+35+64000+45.5)

Evaluating ... ...

[M_Ss1] = 0.00385620965440649

STEP 3: Convert Result to Output's Unit

0.00385620965440649 Mole per Cubic Meter -->3.85620965440649E-06 Mole per Liter (Check conversion here)

FINAL ANSWER

3.85620965440649E-06 ≈ 3.9E-6 Mole per Liter <-- Concentration of Singlet State

(Calculation completed in 00.004 seconds)

You are here -

Home » Chemistry » Physical Chemistry » Physical spectroscopy » Emission Spectroscopy » Singlet State Concentration

Credits

Created by Torsha_Paul

University of Calcutta (CU), Kolkata

Torsha_Paul has created this Calculator and 200+ more calculators!

Verified by Prerana Bakli

University of Hawaiʻi at Mānoa (UH Manoa), Hawaii, USA

Prerana Bakli has verified this Calculator and 1600+ more calculators!

< Emission Spectroscopy Calculators

Degree of Exciplex Formation

LaTeX Go Degree of Exciplex Formation = (Equilibrium Constant for Coordinate Complexes*Quencher Concentration given Degree of Exciplex)/(1+(Equilibrium Constant for Coordinate Complexes*Quencher Concentration given Degree of Exciplex))

Collisional Energy Transfer

LaTeX Go Rate of Collisional Energy Transfer = Quenching Constant*Quencher Concentration given Degree of Exciplex*Singlet State Concentration

Difference in Acidity between Ground and Excited State

LaTeX Go Difference in pka = pKa of Excited State-pKa of Ground State

Equilibrium Constant for Exciplex Formation

LaTeX Go Equilibrium Constant for Coordinate Complexes = 1/(1-Degree of Exciplex Formation)-1

< Fluoroscence and Phosphorescence Calculators

Initial Intensity given Degree of Exciplex Formation

LaTeX Go Initial Intensity given Degree of Exciplex = Rate Constant of Fluoroscence*Equilibrium Constant for Coordinate Complexes/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction)

Fluoroscence Intensity without Quenching

LaTeX Go Intensity Without Quenching = (Rate Constant of Fluoroscence*Absorption Intensity)/(Rate Constant of Non Radiative Reaction+Rate Constant of Fluoroscence)

Fluoroscence Intensity

LaTeX Go Fluorosence Intensity = (Rate Constant of Fluoroscence*Absorption Intensity)/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction)

Fluorescence Rate Constant

LaTeX Go Rate Constant of Fluoroscence = Rate of Fluoroscence/Singlet State Concentration

Singlet State Concentration Formula

LaTeX Go

What is Absorbance ?

Absorbance is defined as "the logarithm of the ratio of incident to transmitted radiant power through a sample (excluding the effects on cell walls)". Alternatively, for samples which scatter light, absorbance may be defined as "the negative logarithm of one minus absorptance, as measured on a uniform sample".

What is Fluoroscence ?

Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, than the absorbed radiation.

How to Calculate Singlet State Concentration?

Singlet State Concentration calculator uses Concentration of Singlet State = Absorption Intensity/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction+Rate Constant of Intersystem Crossing+Rate Constant of Internal Conversion) to calculate the Concentration of Singlet State, The Singlet State Concentration formula is defined as is the number of molecules present in the singlet excited state. The concentration of a substance is the quantity of solute present in a given quantity of solution. Concentrations are usually expressed in terms of molarity, defined as the number of moles of solute in 1 L of solution. Concentration of Singlet State is denoted by [M_Ss1] symbol.

How to calculate Singlet State Concentration using this online calculator? To use this online calculator for Singlet State Concentration, enter Absorption Intensity (I_a), Rate Constant of Fluoroscence (K_f), Rate Constant of Non Radiative Reaction (K_NR), Rate Constant of Intersystem Crossing (K_ISC) & Rate Constant of Internal Conversion (K_IC) and hit the calculate button. Here is how the Singlet State Concentration calculation can be explained with given input values -> 3.9E-9 = 250/(750+35+64000+45.5).

FAQ

What is Singlet State Concentration?

The Singlet State Concentration formula is defined as is the number of molecules present in the singlet excited state. The concentration of a substance is the quantity of solute present in a given quantity of solution. Concentrations are usually expressed in terms of molarity, defined as the number of moles of solute in 1 L of solution and is represented as [M_Ss1] = I_a/(K_f+K_NR+K_ISC+K_IC) or Concentration of Singlet State = Absorption Intensity/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction+Rate Constant of Intersystem Crossing+Rate Constant of Internal Conversion). Absorption Intensity obtained by integrating the area under the absorption line—is proportional to the amount of the absorbing substance present, Rate Constant of Fluoroscence is the rate at which spontaneous emission occurs, Rate Constant of Non Radiative Reaction is defined as the rate at which deactivation occurs in the form of heat energy, Rate Constant of Intersystem Crossing is the rate of decay from excited singlet electronic state to triplet state & Rate Constant of Internal Conversion is the rate of decay from excited singlet electronic state to triplet state.

How to calculate Singlet State Concentration?

The Singlet State Concentration formula is defined as is the number of molecules present in the singlet excited state. The concentration of a substance is the quantity of solute present in a given quantity of solution. Concentrations are usually expressed in terms of molarity, defined as the number of moles of solute in 1 L of solution is calculated using Concentration of Singlet State = Absorption Intensity/(Rate Constant of Fluoroscence+Rate Constant of Non Radiative Reaction+Rate Constant of Intersystem Crossing+Rate Constant of Internal Conversion). To calculate Singlet State Concentration, you need Absorption Intensity (I_a), Rate Constant of Fluoroscence (K_f), Rate Constant of Non Radiative Reaction (K_NR), Rate Constant of Intersystem Crossing (K_ISC) & Rate Constant of Internal Conversion (K_IC). With our tool, you need to enter the respective value for Absorption Intensity, Rate Constant of Fluoroscence, Rate Constant of Non Radiative Reaction, Rate Constant of Intersystem Crossing & Rate Constant of Internal Conversion and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.

Home

FREE PDFs

🔍 Search