Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference Solution

STEP 0: Pre-Calculation Summary
Formula Used
Cathodic Activity Coefficient = (exp((EMF of Cell*[Faraday])/(2*Transport Number of Anion*[R])))*((Anodic Electrolyte Molality*Anodic Activity Coefficient)/Cathodic Electrolyte Molality)
γ2 = (exp((Ecell*[Faraday])/(2*t-*[R])))*((m1*γ1)/m2)
This formula uses 3 Constants, 1 Functions, 6 Variables
Constants Used
[Faraday] - Faraday constant Value Taken As 96485.33212 Coulomb / Mole
[R] - Universal gas constant Value Taken As 8.31446261815324 Joule / Kelvin * Mole
e - Napier's constant Value Taken As 2.71828182845904523536028747135266249
Functions Used
exp - Exponential function, exp(Number)
Variables Used
Cathodic Activity Coefficient - The Cathodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the cathodic half cell.
EMF of Cell - (Measured in Volt) - The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell.
Transport Number of Anion - The Transport Number of Anion is ratio of current carried by anion to total current.
Anodic Electrolyte Molality - (Measured in Mole per Kilogram) - The Anodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the anodic cell.
Anodic Activity Coefficient - The Anodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the anodic half cell.
Cathodic Electrolyte Molality - (Measured in Mole per Kilogram) - The Cathodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the cathodic cell.
STEP 1: Convert Input(s) to Base Unit
EMF of Cell: 0.51 Volt --> 0.51 Volt No Conversion Required
Transport Number of Anion: 49 --> No Conversion Required
Anodic Electrolyte Molality: 0.4 Mole per Kilogram --> 0.4 Mole per Kilogram No Conversion Required
Anodic Activity Coefficient: 5.5 --> No Conversion Required
Cathodic Electrolyte Molality: 0.13 Mole per Kilogram --> 0.13 Mole per Kilogram No Conversion Required
STEP 2: Evaluate Formula
Substituting Input Values in Formula
γ2 = (exp((Ecell*[Faraday])/(2*t-*[R])))*((m11)/m2) --> (exp((0.51*[Faraday])/(2*49*[R])))*((0.4*5.5)/0.13)
Evaluating ... ...
γ2 = 2.85690904850873E+27
STEP 3: Convert Result to Output's Unit
2.85690904850873E+27 --> No Conversion Required
FINAL ANSWER
2.85690904850873E+27 <-- Cathodic Activity Coefficient
(Calculation completed in 00.015 seconds)

Credits

Created by Prashant Singh
K J Somaiya College of science (K J Somaiya), Mumbai
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Verified by Prerana Bakli
National Institute of Technology (NIT), Meghalaya
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10+ Activity of Electrolytes Calculators

Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference
Cathodic Activity Coefficient = (exp((EMF of Cell*[Faraday])/(2*Transport Number of Anion*[R])))*((Anodic Electrolyte Molality*Anodic Activity Coefficient)/Cathodic Electrolyte Molality) Go
Activity Coefficient of Anodic Electrolyte of Concentration Cell with Transference
Anodic Activity Coefficient = ((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/Anodic Electrolyte Molality)/(exp((EMF of Cell*[Faraday])/(2*Transport Number of Anion*[R]))) Go
Activity Coefficient of Cathodic Electrolyte of Concentration Cell without Transference
Cathodic Activity Coefficient = (exp((EMF of Cell*[Faraday])/(2*[R]*Temperature)))*((Anodic Electrolyte Molality*Anodic Activity Coefficient)/Cathodic Electrolyte Molality) Go
Activity Coefficient of Anodic Electrolyte of Concentration Cell without Transference
Anodic Activity Coefficient = ((Cathodic Electrolyte Molality*Cathodic Activity Coefficient)/Anodic Electrolyte Molality)/(exp((EMF of Cell*[Faraday])/(2*[R]*Temperature))) Go
Activity of Cathodic Electrolyte of Concentration Cell with Transference
Cathodic Ionic Activity = (exp((EMF of Cell*[Faraday])/(Transport Number of Anion*[R]*Temperature)))*Anodic Ionic Activity Go
Activity of Anodic Electrolyte of Concentration Cell with Transference
Anodic Ionic Activity = Cathodic Ionic Activity/(exp((EMF of Cell*[Faraday])/(Transport Number of Anion*[R]*Temperature))) Go
Activity of Cathodic Electrolyte of Concentration Cell without Transference
Cathodic Ionic Activity = Anodic Ionic Activity*(exp((EMF of Cell*[Faraday])/([R]*Temperature))) Go
Activity of Anodic Electrolyte of Concentration Cell without Transference
Anodic Ionic Activity = Cathodic Ionic Activity/(exp((EMF of Cell*[Faraday])/([R]*Temperature))) Go
Activitiy of Electrolyte given Concentration and Fugacity
Ionic Activity = (Actual Concentration^2)*(Fugacity^2) Go
Activity Coefficient given Ionic Activity
Activity Coefficient = (Ionic Activity/Molality) Go

Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference Formula

Cathodic Activity Coefficient = (exp((EMF of Cell*[Faraday])/(2*Transport Number of Anion*[R])))*((Anodic Electrolyte Molality*Anodic Activity Coefficient)/Cathodic Electrolyte Molality)
γ2 = (exp((Ecell*[Faraday])/(2*t-*[R])))*((m1*γ1)/m2)

What is concentration cell with transference?

A cell in which the transference of a substance from a system of high concentration to one at low concentration results in the production of electrical energy is called a concentration cell. It consists of two half cells having two identical electrodes and identical electrolytes but with different concentrations. EMF of this cell depends upon the difference of concentration. In a concentration cell with transference, there is a direct transference of electrolytes. The same electrode is reversible with respect to one of the ions of the electrolyte.

How to Calculate Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference?

Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference calculator uses Cathodic Activity Coefficient = (exp((EMF of Cell*[Faraday])/(2*Transport Number of Anion*[R])))*((Anodic Electrolyte Molality*Anodic Activity Coefficient)/Cathodic Electrolyte Molality) to calculate the Cathodic Activity Coefficient, The Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference with transference formula is defined as the relation with emf of the cell and with the transport number of the anion in the electrolytic solution. Cathodic Activity Coefficient is denoted by γ2 symbol.

How to calculate Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference using this online calculator? To use this online calculator for Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference, enter EMF of Cell (Ecell), Transport Number of Anion (t-), Anodic Electrolyte Molality (m1), Anodic Activity Coefficient 1) & Cathodic Electrolyte Molality (m2) and hit the calculate button. Here is how the Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference calculation can be explained with given input values -> 2.9E+27 = (exp((0.51*[Faraday])/(2*49*[R])))*((0.4*5.5)/0.13).

FAQ

What is Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference?
The Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference with transference formula is defined as the relation with emf of the cell and with the transport number of the anion in the electrolytic solution and is represented as γ2 = (exp((Ecell*[Faraday])/(2*t-*[R])))*((m1*γ1)/m2) or Cathodic Activity Coefficient = (exp((EMF of Cell*[Faraday])/(2*Transport Number of Anion*[R])))*((Anodic Electrolyte Molality*Anodic Activity Coefficient)/Cathodic Electrolyte Molality). The EMF of Cell or electromotive force of a cell is the maximum potential difference between two electrodes of a cell, The Transport Number of Anion is ratio of current carried by anion to total current, The Anodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the anodic cell, The Anodic Activity Coefficient is a factor used in thermodynamics to account for deviations from ideal behaviour in a mixture of chemical substances in the anodic half cell & The Cathodic Electrolyte Molality is defined as the total number of moles of solute per kilogram of solvent present in the solution of the cathodic cell.
How to calculate Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference?
The Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference with transference formula is defined as the relation with emf of the cell and with the transport number of the anion in the electrolytic solution is calculated using Cathodic Activity Coefficient = (exp((EMF of Cell*[Faraday])/(2*Transport Number of Anion*[R])))*((Anodic Electrolyte Molality*Anodic Activity Coefficient)/Cathodic Electrolyte Molality). To calculate Activity Coefficient of Cathodic Electrolyte of Concentration Cell with Transference, you need EMF of Cell (Ecell), Transport Number of Anion (t-), Anodic Electrolyte Molality (m1), Anodic Activity Coefficient 1) & Cathodic Electrolyte Molality (m2). With our tool, you need to enter the respective value for EMF of Cell, Transport Number of Anion, Anodic Electrolyte Molality, Anodic Activity Coefficient & Cathodic Electrolyte Molality and hit the calculate button. You can also select the units (if any) for Input(s) and the Output as well.
How many ways are there to calculate Cathodic Activity Coefficient?
In this formula, Cathodic Activity Coefficient uses EMF of Cell, Transport Number of Anion, Anodic Electrolyte Molality, Anodic Activity Coefficient & Cathodic Electrolyte Molality. We can use 1 other way(s) to calculate the same, which is/are as follows -
  • Cathodic Activity Coefficient = (exp((EMF of Cell*[Faraday])/(2*[R]*Temperature)))*((Anodic Electrolyte Molality*Anodic Activity Coefficient)/Cathodic Electrolyte Molality)
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